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Chemistry, Properties and Tests of Precious Stones

<h2>CHAPTER XIV.</h2> <h3>VARIOUS PRECIOUS STONES—continued.</h3> <h4>The Chrysoberyl.</h4> There are certain stones and other minerals which, owing to their possession of numerous microscopically fine cavities, of a globular or tubular shape, have the appearance of "rays" or "stars," and these are called "asteriated." Several of such stones have been discussed already in the last chapter, and in addition to these star-like rays, some of the stones have, running through their substance, one or more streaks, perhaps of asbestos or calcite, some being perfectly clear, whilst others are opalescent. When these streaks pass across the star-like radiations they give the stone the appearance of an eye, the rays forming the iris, the clear, opalescent, or black streak closely resembling the slit in a cat's eye, and when these stones are cut en cabochon, that is, dome-shaped (see Chapter XI. on "Cutting"), there is nothing to deflect the light beams back and forth from facet to facet, as in a diamond, so that the light, acting directly on these radiations or masses of globular cavities and on the streak, causes the former to glow like living fire, and the streak appears to vibrate, palpitate,[Pg 89] expand, and contract, exactly like the slit in the eye of a cat. There are a considerable number of superstitions in connection with these cat's-eye stones, many people regarding them as mascots, or with disfavour, according to their colour. When possessing the favourite hue or "fire" of the wearer, such as the fire of the opal for those born in October, of the ruby for those born in July, etc., these stones are considered to bring nothing but good luck; to ward off accident, danger, and sudden death; to be a charm against being bitten by animals, and to be a protection from poison, the "evil eye," etc. They figured largely, along with other valuable jewels, in the worship of the ancient Egyptians, and have been found in some of the tombs in Egypt. They also appeared on the "systrum," which was a sacred instrument used by the ancient Egyptians in the performance of their religious rites, particularly in their sacrifices to the goddess Isis. This, therefore, may be considered one of their sacred stones, whilst there is some analogy between the cat's-eye stones and the sacred cat of the Egyptians which recurs so often in their hieroglyphics; it is well known that our domestic cat is not descended from the wild cat, but from the celebrated cat of Egypt, where history records its being "domesticated" at least thirteen centuries B.C. From there it was taken throughout Europe, where it appeared at least a century B.C., and was kept as a pet in the homes of the wealthy, though certain writers, speaking of the "mouse-hunters" of the old Romans and Greeks, state that these creatures were not the Egyptian cat, but a carniverous, long-bodied[Pg 90] animal, after the shape of a weasel, called "marten," of the species the "beech" or "common" marten (mustela foina), found also in Britain to-day. It is also interesting to note that the various superstitions existing with regard to the different varieties and colours of cats also exist in an identical manner with the corresponding colours of the minerals known as "cat's eye." Several varieties of cat's-eye have already been described. Another important variety is that of the chrysoberyl called "cymophane." This is composed of glucina, which is glucinum oxide, or beryllia, BeO, of which there is 19.8 per cent., and alumina, or aluminium oxide, Al2O3, of which there is 80.2 per cent. It has, therefore, the chemical formula, BeO,Al2O3. This stone shows positive electricity when rubbed, and, unlike the sapphires described in the last chapter, which lose their colour when heated, this variety of chrysoberyl shows no change in colour, and any electricity given to it, either by friction or heat, is retained for a long time. When heated in the blowpipe alone it remains unaltered, that is, it is not fusible, and even with microcosmic salt it requires a considerably long and fierce heat before it yields and fuses, and acids do not act upon it. It crystallises in the 4th (rhombic) system, and its lustre is vitreous. The cymophane shows a number of varieties, quite as many as the chrysoberyl, of which it is itself a variety, and these go through the gamut of greens, from a pale white green to the stronger green of asparagus, and through both the grey and yellow greens to dark. It is found in Ceylon, Moravia, the Ural Mountains, Brazil,[Pg 91] North America, and elsewhere. The cat's-eye of this is very similar to the quartz cat's-eye, but a comparison will make the difference so clear that they could never be mistaken, apart from the fact that the quartz has a specific gravity considerably lower than the chrysoberyl cat's-eye, which latter is the true cat's-eye, and the one usually understood when allusion is made to the stone without any distinguishing prefix, such as the ruby, sapphire, quartz, etc., cat's eye. It should, however, be mentioned that this stone is referred to when the names Ceylonese and Oriental cat's-eye are given, which names are used in the trade as well as the simple appellation, "cat's eye." One peculiarity of some of these stones is that the "fire" or "glow" is usually altered in colour by the colour of the light under which it is seen, the change of colour being generally the complementary. Thus, a stone which in one light shows red, in another will be green; the "eye" showing blue in one light will become orange in another; whilst the yellow of another stone may show a decided purple or amethyst in a different light. A good test for this, and indeed most precious stones, is that they conduct heat more quickly than does glass, and with such rapidity that on breathing upon a stone the warmth is conducted instantly, so that, though the stone is dimmed the dimness vanishes at once, whereas with glass the film of moisture fades but slowly in comparison. <h4>The Topaz.</h4> The name topaz is derived from the Greek topazos, which is the name of a small island situated in the Gulf[Pg 92] of Arabia, from whence the Romans obtained a mineral which they called topazos and topazion, which mineral to-day is termed chrysolite. The mineral topaz is found in Cornwall and in the British Isles generally; also in Siberia, India, South America and many other localities, some of the finest stones coming from Saxony, Bohemia, and Brazil, especially the last-named. The cleavage is perfect and parallel to the basal plane. It crystallises in the 4th (rhombic) system; in lustre it is vitreous; it is transparent, or ranging from that to translucent; the streak is white or colourless. Its colour varies very much—some stones are straw-colour, some are grey, white, blue, green, and orange. A very favourite colour is the pink, but in most cases this colour is not natural to the stone, but is the result of "burning," or "pinking" as the process is called technically, which process is to raise the temperature of a yellow stone till the yellow tint turns to a pink of the colour desired. The topaz is harder than quartz, as will be seen on reference to the "Hardness" table, and is composed of a silicate of aluminium, fluorine taking the place of some of the oxygen. Its composition averages 16.25 per cent. of silica, 55.75 per cent. of alumina, or oxide of aluminium, and fluoride of silicium, 28 per cent. Its formula is [Al(F,OH)]2 SiO4, or (AlF)2SiO4. From this it will be understood that the fluorine will be evolved when the stone is fused. It is, however, very difficult to fuse, and alone it is infusible under the blowpipe, but with microcosmic salt it fuses and evolves fluorine, and the glass of the tube in the open end of which the stone is fixed is bitten with the gas.[Pg 93] Such experiments with the topaz are highly interesting, and if we take a little of the powdered stone and mix with it a small portion of the microcosmic salt, we may apply the usual test for analysing and proving aluminium, thus: a strongly brilliant mass is seen when hot, and if we moisten the powder with nitrate of cobalt and heat again, this time in the inner flame, the mass becomes blue. Other phenomena are seen during the influence of heat. Some stones, as stated, become pink on heating, but if the heating is continued too long, or too strongly, the stone is decoloured. Others, again, suffer no change, and this has led to a slight difference of opinion amongst chemists as to whether the colour is due to inorganic or organic matter. Heating also produces electricity, and the stone, and even splinters of it, will give out a curious phosphorescent light, which is sometimes yellow, sometimes blue, or green. Friction or pressure produces strong electrification; thus the stones may be electrified by shaking a few together in a bag, or by the tumbling of the powdered stone-grains over each other as they roll down a short inclined plane. The stones are usually found in the primitive rocks, varying somewhat in different localities in their colour; many of the Brazilian stones, when cut as diamonds, are not unlike them. In testing, besides those qualities already enumerated, the crystalline structure is specially perfect and unmistakable. It is doubly refractive, whereas spinel and the diamond, which two it closely resembles, are singly refractive. Topaz is readily electrified, and, if perfect at terminals, becomes polarised; also the commercial[Pg 94] solution of violets, of which a drop only need be taken for test, is turned green by adding to it a few grains of topaz dust, or of a little splinter crushed to fine powder. <h4>The Beryl.</h4> The beryl is a compound of silicates of beryllia and alumina, with the formula 3BeOSiO2 + Al2O3,3SiO2, or 3BeO,Al2O3,6SiO2. It differs very little indeed from the emerald, with the exception of its colour. In the ordinary varieties this is somewhat poor, being mostly blue, or a dirty or a greenish yellow; the better kinds, however, possess magnificent colour and variety, such as in the aquamarine, emerald, etc. The cleavage is parallel to the basal plane. Its lustre is sometimes resinous, sometimes vitreous, and it crystallises in the 2nd (hexagonal) system. It occurs in somewhat long, hexagonal prisms, with smooth, truncated planes, and is often found in granite and the silt brought down by rivers from granite, gneiss, and similar rocks. It is found in Great Britain and in many parts of Europe, Asia, and America, in crystals of all sizes, from small to the weight of several tons. The common kinds are too opaque and colourless to be used as gems and are somewhat difficult of fusion under the blowpipe, on the application of which heat some stones lose their colour altogether, others partly; others, which before heating were somewhat transparent, become clouded and opaque; others suffer no change in colour, whilst some are improved. In almost every case a slight fusion is seen on the sharp edges of fractures, which become smooth, lose their sharpness, and have the appearance of partly fused[Pg 95] glass. The hardness varies from 7-1/4 to 8, the crystals being very brittle, breaking with a fracture of great unevenness. The better varieties are transparent, varying from that to translucent, and are called the "noble" beryls. Transparent beryl crystals are used by fortune-tellers as "gazing stones," in which they claim to see visions of future events. <h4>The Emerald.</h4> Considering the particular emerald which is a variety of beryl—although the name emerald in the trade is applied somewhat loosely to any stone which is of the same colour, or approaching the colour of the beryl variety—this emerald only differs chemically from the beryl, just described, in possessing an addition of oxide of chromium. In shape, crystallisation, fracture and hardness, it is the same, and often contains, in addition to the chromium, the further addition of traces of carbonate of lime, magnesia, and occasionally faint traces of hornblende and mica, which evidently result from its intimate association with the granite rock and gneiss, amongst which it is mostly found, the latter rocks being of a slaty nature, in layers or plates, and, like granite, containing mica, pyrites, felspar, quartz, etc. Emeralds have been known from very early times, and are supposed to have been found first in the mines of ancient Egypt. They were considered amongst the rarest and the most costly of gems, and it was the custom, when conferring lavish honour, to engrave or model emeralds for presentation purposes. Thus we find Pliny describes Ptolemy giving Lucullus, on his landing[Pg 96] at Alexandria, an emerald on which was engraved his portrait. Pliny also relates how the short-sighted Nero watched the fights of gladiators through an eye-glass made of an emerald, and in ancient times, in Rome, Greece, and Egypt, eye-glasses made of emeralds were much valued. Many of these, as well as engraved and carved emeralds, have been discovered in ruins and tombs of those periods. The copper emerald is rare; it is a hydrous form of copper silicate, CuOSiO2 + H2O, of a beautiful emerald green, varying from transparent to translucent. It exhibits double refraction, and is a crystallised mineral, brittle, and showing a green streak. This is less hard than the real emerald, is heavier, deeper in colour, and is usually found in crystals, in cavities of a particular kind of limestone which exists at Altyn-Tübe, a hill in the Altai Mountains, in the Urals, and in North and Central America. <h4>The Tourmaline.</h4> The tourmaline is a most complex substance; almost every stone obtained has a different composition, some varying but slightly, with mere traces of certain constituents which other stones possess in a perceptible degree. Consequently, it is not possible to give the chemical formula, which might, and possibly would, be found but seldom, even in analyses of many specimens. It will therefore be sufficient to state the average composition, which is:—ferrous oxide, manganous oxide, potash, lime, boracic acid, magnesia, soda, lithia, and water. These form, roughly speaking, 25 per cent. of the bulk, the remainder being oxide of silicon and oxide[Pg 97] of aluminium in about equal parts. It crystallises in the 2nd (hexagonal) system, with difficult cleavage and vitreous lustre. It will naturally be expected that a substance of such complexity and variety of composition must necessarily have a corresponding variety of colour; thus we find in this, as in the corundum, a wonderful range of tints. The common is the black, which is not used as a gem. Next come the colourless specimens, which are not often cut and polished, whereas all the transparent and coloured varieties are in great demand. To describe adequately their characteristics with relation to light would alone require the space of a complete volume, and the reader is referred to the many excellent works on physics (optics) which are obtainable. This stone is doubly refracting, exhibiting extremely strong dichroism, especially in the blue and the green varieties. It polarises light, and when viewed with the dichroscope shows a remarkable variety of twin colours. It will be remembered that in Hogarth's "Rake's Progress," the youth is too engrossed in the changing wonders of a tourmaline to notice the entrance of the officers come to arrest him. <hr style="width: 65%;" /> [Pg 98] <div style="break-after:column;"></div>

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